AQA GCSE Chemistry · 4.4

Chemical changes

50 exam-style questions with answers for 4.4 Chemical changes in AQA GCSE Chemistry (spec 8462). Practise with flashcards, a topic quiz, a random quiz across the course, 5 crosswords, or read every question and answer below. Not official AQA material.

All 50 questions and answers

  1. Question 1 · Spec 4.4.1.1 · Metal oxides

    What is oxidation in terms of oxygen? [1 mark]

    Answer:
    The gain of oxygen.
  2. Question 2 · Spec 4.4.1.1 · Metal oxides

    What is reduction in terms of oxygen? [1 mark]

    Answer:
    The loss of oxygen.
  3. Question 3 · Spec 4.4.1.2 · Reactivity series

    Place these in order of reactivity, most reactive first: copper, potassium, zinc, magnesium. [1 mark]

    Answer:
    Potassium, magnesium, zinc, copper.
  4. Question 4 · Spec 4.4.1.2 · Reactivity series

    Why are carbon and hydrogen included in the reactivity series? [1 mark]

    Answer:
    They are non-metals used to compare reactivity, for example carbon can reduce metals below it.
  5. Question 5 · Spec 4.4.1.2 · Reactivity series

    Explain the reactivity of a metal in terms of ions. [1 mark]

    Answer:
    More reactive metals lose electrons more easily to form positive ions.
  6. Question 6 · Spec 4.4.1.2 · Displacement

    What happens when zinc is added to copper sulfate solution? [2 marks]

    Answer:
    Zinc displaces copper, as zinc is more reactive (1); the blue solution fades and a brown/pink coating of copper forms (1).
  7. Question 7 · Spec 4.4.1.3 · Extraction

    How are metals less reactive than carbon extracted? [1 mark]

    Answer:
    By reduction with carbon.
  8. Question 8 · Spec 4.4.1.3 · Extraction

    Why is gold found as the metal itself? [1 mark]

    Answer:
    It is very unreactive.
  9. Question 9 · Spec 4.4.1.3 · Extraction

    Write the word equation for extracting iron from iron oxide using carbon. [1 mark]

    Answer:
    Iron oxide + carbon → iron + carbon dioxide.
  10. Question 10 · Spec 4.4.1.4 · Redox · Higher only

    What are oxidation and reduction in terms of electrons? [2 marks]

    Answer:
    Oxidation is the loss of electrons (1); reduction is the gain of electrons (1).
  11. Question 11 · Spec 4.4.1.4 · Ionic equations · Higher only

    Write the ionic equation for zinc displacing copper ions. [1 mark]

    Answer:
    Zn + Cu²⁺ → Zn²⁺ + Cu.
  12. Question 12 · Spec 4.4.1.4 · Redox · Higher only

    In Zn + Cu²⁺ → Zn²⁺ + Cu, which species is oxidised? [1 mark]

    Answer:
    Zinc (it loses electrons).
  13. Question 13 · Spec 4.4.2.1 · Acids and metals

    Write the word equation for magnesium reacting with hydrochloric acid. [1 mark]

    Answer:
    Magnesium + hydrochloric acid → magnesium chloride + hydrogen.
  14. Question 14 · Spec 4.4.2.1 · Acids and metals · Higher only

    Explain why the reaction of a metal with acid is a redox reaction. [2 marks]

    Answer:
    The metal atoms lose electrons and are oxidised (1); the hydrogen ions gain electrons and are reduced (1).
  15. Question 15 · Spec 4.4.2.2 · Neutralisation

    Write the word equation for copper oxide reacting with sulfuric acid. [1 mark]

    Answer:
    Copper oxide + sulfuric acid → copper sulfate + water.
  16. Question 16 · Spec 4.4.2.2 · Neutralisation

    What are the products when an acid reacts with a metal carbonate? [1 mark]

    Answer:
    A salt, water and carbon dioxide.
  17. Question 17 · Spec 4.4.2.2 · Salts

    Which acid produces chlorides, sulfates and nitrates? [3 marks]

    Answer:
    Hydrochloric acid gives chlorides (1); sulfuric acid gives sulfates (1); nitric acid gives nitrates (1).
  18. Question 18 · Spec 4.4.2.2 · Salts

    Write the formula of calcium nitrate. [1 mark]

    Answer:
    Ca(NO₃)₂.
  19. Question 19 · Spec 4.4.2.3 · Required practical 1

    Describe how to make pure dry copper sulfate crystals from copper oxide. [3 marks]

    Answer:
    Add excess copper oxide to warm sulfuric acid and stir (1); filter to remove the excess copper oxide (1); heat the solution to evaporate some water, then leave to crystallise and pat the crystals dry (1).
  20. Question 20 · Spec 4.4.2.3 · Required practical 1

    Why is the metal oxide added in excess? [1 mark]

    Answer:
    To make sure all the acid has reacted.
  21. Question 21 · Spec 4.4.2.4 · pH

    What range of pH values shows a strong acid and a strong alkali? [2 marks]

    Answer:
    Acids: pH less than 7 (strong around 0–2) (1); alkalis: pH greater than 7 (strong around 12–14) (1).
  22. Question 22 · Spec 4.4.2.4 · Acids and alkalis

    What ions do acids and alkalis produce in aqueous solution? [2 marks]

    Answer:
    Acids produce hydrogen ions, H⁺ (1); alkalis produce hydroxide ions, OH⁻ (1).
  23. Question 23 · Spec 4.4.2.4 · Neutralisation

    Write the ionic equation for neutralisation. [1 mark]

    Answer:
    H⁺(aq) + OH⁻(aq) → H₂O(l).
  24. Question 24 · Spec 4.4.2.4 · pH

    How can the pH of a solution be measured? [1 mark]

    Answer:
    Using universal indicator or a pH probe.
  25. Question 25 · Spec 4.4.2.5 · Required practical 2

    Describe how to carry out a titration. [3 marks]

    Answer:
    Measure 25.0 cm³ of alkali into a conical flask with a pipette and add indicator (1); add acid from a burette until the indicator just changes colour (1); record the volume and repeat to get concordant results (1).
  26. Question 26 · Spec 4.4.2.6 · Strong and weak acids · Higher only

    What is the difference between a strong and a weak acid? [2 marks]

    Answer:
    A strong acid is completely ionised in aqueous solution (1); a weak acid is only partially ionised (1).
  27. Question 27 · Spec 4.4.2.6 · Strong and weak acids · Higher only

    Give an example of a strong acid and a weak acid. [2 marks]

    Answer:
    Strong: hydrochloric, nitric or sulfuric acid (1); weak: ethanoic, citric or carbonic acid (1).
  28. Question 28 · Spec 4.4.2.6 · pH · Higher only

    How does the H⁺ concentration change when pH decreases by 1? [1 mark]

    Answer:
    It increases by a factor of 10.
  29. Question 29 · Spec 4.4.2.6 · Concentrated and strong · Higher only

    What is the difference between a concentrated acid and a strong acid? [2 marks]

    Answer:
    Concentration is the amount of acid in a given volume of water (1); strength is how fully the acid ionises (1).
  30. Question 30 · Spec 4.4.3.1 · Electrolysis

    What is electrolysis? [2 marks]

    Answer:
    The breakdown of an ionic compound using electricity (1); when it is melted or dissolved, so the ions can move to the electrodes (1).
  31. Question 31 · Spec 4.4.3.1 · Electrolysis

    Which ions move to the cathode and which to the anode? [2 marks]

    Answer:
    Positive ions move to the negative cathode (1); negative ions move to the positive anode (1).
  32. Question 32 · Spec 4.4.3.2 · Molten compounds

    Name the products of the electrolysis of molten lead bromide. [2 marks]

    Answer:
    Lead at the cathode (1); bromine at the anode (1).
  33. Question 33 · Spec 4.4.3.3 · Aluminium extraction

    Why is aluminium extracted by electrolysis? [1 mark]

    Answer:
    It is more reactive than carbon, so it cannot be reduced by carbon.
  34. Question 34 · Spec 4.4.3.3 · Aluminium extraction

    Why is aluminium oxide mixed with cryolite? [1 mark]

    Answer:
    To lower the melting point, saving energy.
  35. Question 35 · Spec 4.4.3.3 · Aluminium extraction

    Why must the carbon anodes be replaced regularly? [1 mark]

    Answer:
    Oxygen produced at the anode reacts with the carbon, making carbon dioxide, so the anodes burn away.
  36. Question 36 · Spec 4.4.3.4 · Aqueous solutions

    What is produced at the cathode in the electrolysis of aqueous solutions? [2 marks]

    Answer:
    The metal, if it is less reactive than hydrogen (1); otherwise hydrogen gas (1).
  37. Question 37 · Spec 4.4.3.4 · Aqueous solutions

    What is produced at the anode in the electrolysis of aqueous solutions? [2 marks]

    Answer:
    The halogen, if halide ions are present (1); otherwise oxygen (1).
  38. Question 38 · Spec 4.4.3.4 · Brine

    Name the three products of the electrolysis of sodium chloride solution. [3 marks]

    Answer:
    Hydrogen at the cathode (1); chlorine at the anode (1); sodium hydroxide left in solution (1).
  39. Question 39 · Spec 4.4.3.4 · Required practical 3

    Describe how to test the gases produced in the electrolysis of an aqueous solution. [2 marks]

    Answer:
    Hydrogen gives a squeaky pop with a lighted splint (1); chlorine bleaches damp litmus paper (oxygen relights a glowing splint) (1).
  40. Question 40 · Spec 4.4.3.5 · Half equations · Higher only

    Write the half equation at the cathode for the electrolysis of molten aluminium oxide. [1 mark]

    Answer:
    Al³⁺ + 3e⁻ → Al.
  41. Question 41 · Spec 4.4.3.5 · Half equations · Higher only

    Write the half equation for chloride ions at the anode. [1 mark]

    Answer:
    2Cl⁻ → Cl₂ + 2e⁻.
  42. Question 42 · Spec 4.4.3.5 · Half equations · Higher only

    Is the reaction at the cathode oxidation or reduction? [1 mark]

    Answer:
    Reduction, because ions gain electrons.
  43. Question 43 · Spec 4.4.2.1 · Acids and metals

    Why do metals like copper not react with dilute acids? [1 mark]

    Answer:
    Copper is less reactive than hydrogen.
  44. Question 44 · Spec 4.4.2.2 · Neutralisation

    Write the balanced equation for sodium hydroxide reacting with hydrochloric acid. [1 mark]

    Answer:
    NaOH + HCl → NaCl + H₂O.
  45. Question 45 · Spec 4.4.1.2 · Reactivity series

    Describe the reaction of potassium with water. [2 marks]

    Answer:
    It reacts very vigorously, catching fire with a lilac flame (1); producing potassium hydroxide and hydrogen (1).
  46. Question 46 · Spec 4.4.2.5 · Titration

    Why is a pipette used to measure the alkali in a titration? [1 mark]

    Answer:
    It measures a fixed volume very accurately.
  47. Question 47 · Spec 4.4.3.2 · Molten compounds

    Why must ionic compounds be molten or dissolved for electrolysis? [1 mark]

    Answer:
    The ions must be free to move to the electrodes.
  48. Question 48 · Spec 4.4.3.4 · Aqueous solutions

    Predict the product at the cathode when copper sulfate solution is electrolysed. [1 mark]

    Answer:
    Copper, because it is less reactive than hydrogen.
  49. Question 49 · Spec 4.4.2.4 · Indicators

    What colour is universal indicator in a neutral solution? [1 mark]

    Answer:
    Green.
  50. Question 50 · Spec 4.4.3.3 · Aluminium extraction

    Why is extracting aluminium expensive? [1 mark]

    Answer:
    It uses large amounts of electricity to melt the ore and to carry out electrolysis.

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